{"id":71199,"date":"2017-01-10T08:45:21","date_gmt":"2017-01-10T08:45:21","guid":{"rendered":"http:\/\/icia.ro\/?p=71199"},"modified":"2017-01-17T09:57:04","modified_gmt":"2017-01-17T09:57:04","slug":"99-evaluarea-biodisponibilitatii-metalelor-sol-si-sedimente-utilizand-tehnica-gradientilor-de-difuzie-straturi-subtiri-extractii-chimice-si-metode-biologice-biomet","status":"publish","type":"post","link":"https:\/\/icia.ro\/en\/2017\/01\/10\/99-evaluarea-biodisponibilitatii-metalelor-sol-si-sedimente-utilizand-tehnica-gradientilor-de-difuzie-straturi-subtiri-extractii-chimice-si-metode-biologice-biomet\/","title":{"rendered":"Assessment of metals bioavailability in soils and sediments using Diffusive Gradients in Thin-films technique, chemical extractions and biological methods , BIOMET"},"content":{"rendered":"

Objectives:
\nStudies have demonstrated that biological effects are not related to the total concentration of a contaminant in the environment. Biological responses of organisms have been shown to be related to the concentration of labile metal species in environment and, at international level is expressed the need to evaluate risk of exposure to toxic metals in terms of their bioavailability.<\/p>\n

<\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n\n
OBJECTIVES<\/b><\/td>\nOverall objective<\/b>: The development and validation of methods for study metals bioavailability in soils and sediments using Diffusively Gradients in Thin-films technique and correlation with traditionally applied methods based on chemical extraction and accumulation in biota.<\/p>\n

Specific objectives:<\/b><\/p>\n

    \n
  • development and validation of DGT and other chemical extraction techniques for assessment of metals bioavailability in soil and sediments through collaborative studies;<\/li>\n
  • development and validation of spectrometric techniques used in metals measurements (ICP-OES, ICP-MS, LA-ICP-MS);<\/li>\n
  • applying of methods in a case study, in a polluted mining area, and making correlations between metals bioavailability in soil and the metals accumulated in fungi or plants grown on polluted soils;<\/li>\n
  • results dissemination by common scientific papers;<\/li>\n
  • preparation of joint international projects, to be submitted to EU-FP7 or other European programs and initiatives.<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n
<\/td>\n<\/tr>\n
DESCRIPTION<\/b><\/td>\nStudies have demonstrated that biological effects are not related to the total concentration of a contaminant in the environment. Biological responses of organisms have been shown to be related to the concentration of labile metal species in environment and, at international level is expressed the need to evaluate risk of exposure to toxic metals in terms of their bioavailability.
\nEven if various methods for bioavailability are presented in literature, no generally accepted method was established, and thus the development and validation of methods especially for the field trials is of a great interest. Through the present project it is proposed a comparative study of effectiveness of different techniques for assessment of metals bioavailability in soils and sediment, and to correlate the potentially bioavailable metals with the bioaccumulation in plants and fungi.
\nThe BIOMET <\/b>project proposes the development and validation of methods for the study of metal mobility and bioavailability in soils and sediments by joint research efforts of Romanian and Slovak researchers.<\/td>\n<\/tr>\n
<\/td>\n<\/tr>\n
RESULTS ESTIMATED<\/b><\/td>\n\n
    \n
  • validated methods for extraction of bioavailable fraction of metals;<\/li>\n
  • validated spectrometric techniques used for metals determination in soil and sediments extracts;<\/li>\n
  • bioavailable fraction of metals assessed in soils and sediments from polluted areas;<\/li>\n
  • correlations between metals bioavailability assessed by chemical methods with metals bioaccumulation in plants;<\/li>\n
  • results disseminated by scientific papers and conference presentations;<\/li>\n
  • draft of proposal of joint international projects.<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n
<\/td>\n<\/tr>\n
RESULTS OBTAINED<\/b><\/td>\n\n
Stage I<\/b><\/div>\n
    \n
  • validated methods for extraction of bioavailable fraction of metals;<\/li>\n
  • validated spectrometric techniques used for metals determination in soil and sediments extracts;<\/li>\n
  • scientific paper accepted at the Conference: Analysis in geology and in environment, Spisska Nova Ves, Slovenia, 13- 15.11.2013, entitled: EVALUATION OF MERCURY BIOAVAILABILITY IN SOIL SAMPLES USING DGT AND TD-AAS TECHNIQUES, authors: Marin Senila, Mirela Miclean, Lacrimioara Senila, Martin Urik, Peter Matus.<\/li>\n<\/ul>\n

    Stage II<\/b><\/p>\n

      \n
    • Report on experimental conditions for using DGT technique and chemical extractions;<\/li>\n
    • Experimentation and validation reports for DGT and chemical extractions;<\/li>\n
    • 12 communications at international conferences;<\/li>\n
    • Trained personnel;<\/li>\n
    • Report on total and bioavailable metals fractions in soil and sediments and metals accumulated by plants;<\/li>\n
    • Draft for international project proposal;<\/li>\n
    • Technical and economic report.<\/li>\n<\/ul>\n

      Communications at International Conferences:<\/p>\n

        \n
      1. ASSESSMENT OF ALUMINIUM BIOLEACHING BY THE FILAMENTOUS FUNGUS USING FLAME ATOMIC ABSORPTION SPECTROMETRY, autori: Ivana Pifkov\u00e1, Martin Ur\u00edk, Marek Bujdo\u0161, Barbora Milov\u00e1, Mirela Miclean, Marin Senila, Peter Mat\u00fa\u0161, 15th Czech-Slovak Spectroscopic Conference, 16-21 Martie 2014, Parga, Republica Ceha, Conference Proceeding, pag. 199<\/li>\n
      2. SPECTROCHEMICAL DETERMINATION OF MERCURY IN SELECTED PLANT SPECIES AND SOIL FROM CONTAMINED LOCALITY RUD\u0147ANY-STO\u008eKY (SLOVAKIA), autori: Michal Hlod\u00e1k, Martin Ur\u00edk, Lucia Ko\u0159enkov\u00e1, Mirela Miclean, Marin Senila, Peter Mat\u00fa\u0161, 15th Czech-Slovak Spectroscopic Conference, 16-21 Martie 2014, Parga, Republica Ceha, Conference Proceeding, pag. 200<\/li>\n
      3. Ortu\u0165 v p\u00f4dach a rastlin\u00e1ch v antropog\u00e9nne kontaminovanej oblasti (Rud\u0148any-Por\u00e1\u010d), Michal Hlod\u00e1k, Martin Ur\u00edk, Peter Mat\u00fa\u0161, Lucia Ko\u0159enkov\u00e1, Marin Senila, Marek Bujdo\u0161, Ingrid Hagarov\u00e1, ENVIRONMENTALISTIKA, PRIF 2014, 9.04.2014, Conference Proceeding, pag. 1592 – 1597<\/li>\n
      4. Biol\u00fahovanie antim\u00f3nu z oxyhydroxidov \u009eeleza prostredn\u00edctvom mikroskopickej vl\u00e1knitej huby Aspergillus niger, autori: Barbora Milov\u00e1, Martin Ur\u00edk, Marek Bujdo\u0161, Marin Senila, Peter Mat\u00fa\u0161, ENVIRONMENTALISTIKA, PRIF 2014, 9.04.2014, Conference Proceeding, pag. 1643 – 1648<\/li>\n
      5. L\u00fahovanie hlin\u00edka druhmi Aspergillus clavatus a A. niger, autori: Barbora Milov\u00e1, Ivana Pifkov\u00e1, Martin Ur\u00edk, Marek Bujdo\u0161, Marin Senila, Lacrimioara Senila, Eva Duborsk\u00e1, Jana Dudov\u00e1, Peter Mat\u00fa\u0161, ENVIRONMENTALISTIKA, PRIF 2014, 9.04.2014, Conference Proceeding, pag. 1649 – 1654<\/li>\n
      6. \u0160t\u00fadium bioakumul\u00e1cie, fytotoxicity a predpove\u010f mobility a fytopr\u00edstupnosti ortuti pomocou aplik\u00e1cie jednoduchej extrak\u010dnej met\u00f3dy (0,11 M kyselina octov\u00e1) v syst\u00e9me p\u00f4da-rastlina (Hordeum vulgare L.)., Hlod\u00e1k, M., Ur\u00edk, M., Mat\u00fa\u0161, P., Bujdo\u0161, M., Hagarov\u00e1, I., Boriov\u00e1, K., Senila M., \u0160tudentsk\u00e1 vedeck\u00e1 konferencia PriF UK 2013. Bratislava: Univerzita Komensk\u00e9ho, 1599-1604.<\/li>\n
      7. \u0160pecia\u010dn\u00e1 anal\u00fdza, frakcion\u00e1cia a stanovenie t\u00e1lia vo vod\u00e1ch a p\u00f4dach. In: Analytick\u00e9 met\u00f3dy a zdravie \u010dloveka, Mat\u00fa\u0161, P., Medve\u010f, J., Kali\u0161, M., Bujdo\u0161, M., Hagarov\u00e1, I., Ur\u00edk, M., Senila, M., Kubov\u00e1, J., Bratislava: Slovensk\u00e1 v\u00e1kuov\u00e1 spolo\u010dnos\u0165, 108-109<\/li>\n
      8. Mechanizmy mikrobi\u00e1lneho l\u00fahovania tuh\u00fdch f\u00e1z. In: Analytika v geol\u00f3gii a v \u009eivotnom prostred\u00ed, Pifkov\u00e1, I., Ur\u00edk, M., Kolen\u010d\u00edk, M., Senila, M., Senila, L., Bratislava: \u0160t\u00e1tny geologick\u00fd \u00fastav Dion\u00fdza \u0160t\u00fara, 123-126<\/li>\n
      9. Stanovenie t\u00e1lia vo vod\u00e1ch, p\u00f4dach a biomase s vyu\u009eit\u00edm ET AAS. In: Analytika v geol\u00f3gii a v \u009eivotnom prostred\u00ed, Mat\u00fa\u0161, P., Medve\u010f, J., Bujdo\u0161, M., Hagarov\u00e1, I., Ur\u00edk, M., Kali\u0161, M., Senila, M., Kubov\u00e1, J., Bratislava: \u0160t\u00e1tny geologick\u00fd \u00fastav Dion\u00fdza \u0160t\u00fara, 73-78<\/li>\n
      10. Analytick\u00e1 geoch\u00e9mia ortuti v syst\u00e9me p\u00f4da-rastlina, Hlod\u00e1k, M., Ur\u00edk, M., Mat\u00fa\u0161, P., Bujdo\u0161, M., Hagarov\u00e1, I., Senila, M., Specia\u010dn\u00ed anal\u00fdza 2013. Brno : Spektroskopick\u00e1 spole\u010dnost Jana Marka Marci, 10<\/li>\n
      11. Vyu\u009eitie nano\u010dasticov\u00fdch oxidov v \u0161pecia\u010dnej anal\u00fdze a frakcion\u00e1cii vybran\u00fdch prvkov, Hagarov\u00e1, I., Ur\u00edk, M., Bujdo\u0161, M., \u010caneck\u00e1, L., Boriov\u00e1, K., Pifkov\u00e1, I., Littera, P., Ko\u0159enkov\u00e1, L., Miku\u0161ov\u00e1, P., Divi\u0161, P., Senila, M., Mat\u00fa\u0161, P., Miglierini, M., Kubov\u00e1, J., Specia\u010dn\u00ed anal\u00fdza 2013. Brno : Spektroskopick\u00e1 spole\u010dnost Jana Marka Marci, 21-23<\/li>\n
      12. Microbial Accumulation of Selenium (IV) and Aluminium (III) Bioleached from Various Natural Materials in Presence of Humic, Ur\u00edk, M., Pifkov\u00e1, I., Gardo\u0161ov\u00e1, K., Bujdo\u0161, M., Mat\u00fa\u0161, P., Ko\u0159enkov\u00e1, L., Senila, M., The 21st International Symposium on Environmental Biogeochemistry, Huazhong Agricultural University: Wuhan, 5.<\/li>\n<\/ol>\n<\/td>\n<\/tr>\n
<\/td>\n<\/tr>\n
Other Informations<\/b><\/td>\n<\/td>\n<\/tr>\n
<\/td>\n<\/tr>\n
<\/td>\nAttached documents:<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

<\/p>","protected":false},"excerpt":{"rendered":"

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